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RESEARCH HIGHLIGHTS
 
Dopant extraction using scanning capacitance microscopy.
Growth, Characterization and Interconnection of Nanostructures.
Investigation of Ultra Thin Oxide Properties and its Influence in CMOS ULSI Integrated-Circuits.
Low-frequency noise characterisation of interconnect reliability.
Nanocrystal growth, characterization and application in memory devices.
Near IR Spectroscopic Photon Emission Microscopy for Deep Submicron Devices.
Next Generation Technologies for Semiconductor Inspection and Defect Review.
Novel Electron Sources.
Oxide reliability under high field impulse stressing and application to nonvolatile semiconductor memory device and reliability characterisation.
Photon emission microscopy of biased MOS devices.
Quantum mechanical (Q-M) modelling and characterisation of thin gate oxide and alternative high-k gate dielectrics.
Scanning Electron Acoustic Microscopy for Subsurface Microelectronic Inspection & Failure Analysis.
Scanning Thermal Microscopy for Integrated Circuit Failure Analysis.

 

Project Dopant extraction using scanning capacitance microscopy.
 
Description:

Continual scaling of devices into the deep-submicrometer regime has resulted in the need for two-dimensional (2-D) dopant profiling with nanometer spatial resolution. There are many dopant profiling techniques available currently, but these are essentially one-dimensional methods, e.g. secondary ion mass spectroscopy (SIMS) and spreading resistance profiling. The objective of this project is to develop an accurate 2-D dopant profiling method with high spatial resolution using scanning capacitance microscopy (SCM) measurements. Inverse modelling using the MEDICI device simulation program has been carried out for dopant extraction from measured SCM data using a p-n junction test sample. The results were calibrated (compared) using SIMS data. [Appl. Phys. Lett., vol. 80, no. 25, p. 4837, 2002.]. We are currently investigating the sensitivity of the SCM measurements on the quality of the overlying oxide layer on the test sample and the effects of the tip geometry.


Contact Person:
A/Prof WK Chim

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Project Growth, Characterization and Interconnection of Nanostructures.
Description:

This project aims to develop techniques to make interconnects to nanostructures, ranging from traditional techniques, to more novel techniques using field emission induced growth recently developed at NUS. With the nanowire growth technique, we have already demonstrated the ability to grow sub-10 nm metallic wires on carbon nanotubes, and we aim to generalize, control, and automate the technique to wire nanostructures to external electrodes. We will also grow and explore the properties of a variety of nanotubes and nanorods grown via CVD and VLS processes. This project will provide us with the capability to grow, characterize, connect and study the electrical behaviour of nanostructures.


Contact Person:
A/Prof JTL Thong

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Project: Investigation of Ultra Thin Oxide Properties and its Influence in CMOS ULSI Integrated-Circuits.
 
Description:

Today, the state-of-the-art CMOS Integrated Circuit technology in the industry has 0.18 micron channel length with the gate oxide as thin as 4 nm. It is predicted that a gate oxide thickness of thinner than 3nm will be needed for MOS transistors with a channel length below 0.1 micron. High quality ultra thin oxide becomes one of the bottle-necks for developing the next generation ULSI technology. In this research project, we intend to find the deeper understanding of the ultra thin oxide properties, the new characterization method and new test standard in evaluating the oxide property and lifetime, and to develop new process technologies to form highly reliable gate oxide layer, including the formation of nitride oxide and nitrogen-profile engineering in ultra-thin gate oxide. The influence of ultra-thin oxide properties in designing low power ULSI circuit systems will also be investigated.


Contact Persons: Prof MF Li and A/Prof BJ Cho

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Project: Low-frequency noise characterisation of interconnect reliability.
 
Description:

Advancements in technology have resulted in aggressive down-scaling of device and interconnect dimensions in integrated circuits (ICs). This has resulted in several reliability concerns in thin films used in interconnects and various applications. Examples of such reliability issues are electromigration, stress-induced migration and voiding. One of the first applications of noise measurement for detecting metal film defects was carried out by Vossen (Appl. Phys. Lett., 1973). Subsequent works have shown the viability of using low-frequency noise measurements for detecting electromigration-induced damage. Our work so far has indicated the feasibility of using low-frequency noise measurements for void parameter extraction in aluminum alloy and copper interconnects; such voids could be the result of electromigration or electrostatic discharge (ESD) induced damage. A void-extraction algorithm using combined low-frequency noise and resistance measurement has been developed [J. Electronic Materials, vol. 30, no. 12, p. 1513.]. Most of the noise measurements so far have been conducted at moderately high current densities of about 5 MA/cm2. To conduct the noise measurements at lower current densities that are closer to those encountered under normal operating bias, a more sensitive ac-bridge/lock-in detection setup has been developed and is currently being refined to optimize its performance. This will help in the development of an accurate and robust void parameter extraction model and also to understand the sensitivity of the noise measurements to void shape, void size, stress and other parameters.


Contact Person:
A/Prof WK Chim

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Project: Nanocrystal growth, characterization and application in memory devices.
Description:

The increasing use of portable electronics and embedded systems has resulted in the need for low-power high-density nonvolatile memory devices. Nanocrystal memories, utilizing dimensional scaling of the floating gate to attain observable room temperature threshold voltage shifts upon charge injection and storage, can satisfy such a need. Over the past years, we have carried out research on the formation of germanium (Ge) nanocrystals embedded in silicon oxide synthesized by sputtering and rapid thermal annealing and demonstrated the charge storage effect [Appl. Phys. Lett., vol. 80, no. 11, p. 2014, 2002.]. We have managed to control the size and vertical ordering of the nanocrystals and have also acquired a bit more understanding of the charge storage mechanism in the nanocrystal structures [To appear in Appl. Phys. Lett., vol. 81, no. 19, 2002.]. We are currently investigating the possibility of using such nanocrystal devices for flash memory application. To achieve controllable device characteristics, we are looking at ways to manipulate the arrangement or spatial order of the Ge nanocrystals. We are currently investigating various methods, such as the use of a template mask during Ge sputtering, to achieve lateral spatial ordering of the Ge nanoparticles. This is a collaborative project with staff from the Microelectronics Laboratory and the Singapore-MIT Alliance.

Contact Persons: A/Prof WK Chim and A/Prof WK Choi


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Project: Near IR Spectroscopic Photon Emission Microscopy for Deep Submicron Devices.
 
Description:

Detection of electroluminescence using Photon Emission Microscope(PEM) is a useful technique in the fault isolation. Spectroscopic analysis of photon emission yields additional information on the nature of the emission, which is correlated to the defect mechanism. Furthermore, increasing use of flip chip technology renders the frontside of the device unaccessible, and the silicon substrate is transparent to light with wavelengths longer than 1100nm. This project aims to build a spectroscopic detector to study the emission from devices at wavelengths from 800nm to 1550nm. Low energy emission from deep submicron devices are studied to extract further information, which is yet observed in visible spectroscopic PEM.

Contact Persons: Prof JCH Phang and Prof DSH Chan

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Project: Next Generation Technologies for Semiconductor Inspection and Defect Review.
 
Description:

The feasibility and profitability of the semiconductor manufacturing industry has always hinged on the premise of making products with high throughput, leading-edge feature geometries and high yield targets. It is well-recognised that the real throughput bottlenecks in the manufacturing process lies not in the front-end processing, but rather in the quality assessment defect-tracing and failure analysis cycles. At present, these primarily image-based procedures still rely heavily on the competence of the human operator, with the attendant disadvantages of relatively low throughput, high cost and potential for human error. Hence, it is highly-desired that the cycle times for these fault-finding procedures be continually reduced in other to minimise line down times and also achieve high accuracy of the process at reasonable cost. A strategy that appears to hold much promise is to exploit advances in computing algorithms and hardware performance to incorporate ever higher degrees of computer-based analysis and instrumentation control in order to overcome existing application issues.


Contact Person:
Dr. WK Wong

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Project Novel Electron Sources.
Description:

This project aims to develop and study novel field-emission sources for electron-optical instrumentation. The electron sources are characterized in a custom-built UHV system equipped with an energy analyzer. Nanowire field-emitters of tungsten and carbon grown by a field-emission induced process have demonstrated remarkable stability. In collaboration with the Physics Department, we are also studying the field-emission characteristics of novel metal oxide nanostructures grown by a simple hotplate technique.


Contact Person:
A/Prof JTL Thong

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Project: Oxide reliability under high field impulse stressing and application to nonvolatile semiconductor memory device and reliability characterisation.
 
Description:

There is a trend towards the use of shorter duration pulses and shorter time-between-pulses for the programming of nonvolatile semiconductor memory (NVSM) devices. Pulse duration of 100 ns or smaller has been used for programming of flash and nanocrystal memory devices. Oxide degradation under high field impulses is therefore of particular interest in NVSMs that use tunnelling for the programming of the memory cell. Previous work has shown the increased sensitivity of low-frequency noise measurements for the detection of latent damage in oxides subjected to high field impulse stressing [IEEE Electron Device Lett., vol. 19, no. 10, p. 363, 1998; Jpn. J. Appl. Phys., vol. 40, no. 12, p. 6670.]. The various defect generation and conduction mechanisms responsible for the stress-induced leakage current (SILC) in thin oxides have been investigated [J. Appl. Phys., vol. 91, no. 3, p. 1304 and 1577, 2002.]. Studies were also conducted to understand the trap generation and relaxation processes occurring during high field impulse stresses. An experimental setup for studying the charge storage, charge retention, write/erase endurance and read disturb characteristics of NVSMs has been developed and used for investigating the reliability of NVSMs under high field impulse stressing. The setup is currently being used for the characterisation of germanium nanocrystal memory devices that are fabricated in-house.


Contact Person:
A/Prof WK Chim

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Project: Photon emission microscopy of biased MOS devices.
 
Description:

This project involves the use of the photon emission microscope for studying the electroluminescence from biased MOS devices. Past studies have used the in-house developed setup for investigating the electroluminescence from MOS devices under hot-carrier biasing conditions. A gated photon counting method has also been developed to measure the weak electroluminescence from silicon dioxide. The experimental setup is currently being used to investigate the electroluminescence from germanium nanocrystal structures.


Contact Person:
A/Prof WK Chim

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Project: Quantum mechanical (Q-M) modelling and characterisation of thin gate oxide and alternative high-k gate dielectrics.
 
Description:

Aggressive reduction of device feature sizes has led to MOS devices with gate oxide thickness of less than 5 nm and substrate doping approaching 1018 cm-3. Accurate characterisation (e.g., capacitance-voltage C-V and current-voltage I-V) of such devices will require the modelling of the quantum-confined 2-D electron charges tunnelling into the gate oxide. A Q-M program has been developed for oxide thickness extraction and tunnelling current calculations by solving Poisson's and Schrodinger equations self-consistently. It is predicted that silicon dioxide as a gate dielectric will reach its minimum thickness limit of about 2 nm because of the increasing dominance of the direct tunnelling gate leakage current for such thin oxides. Various high-k dielectric materials (e.g., hafnium oxide, zirconium oxide and their silicates) have been identified as potential replacements for silicon dioxide. Work is currently being carried out to fabricate and characterise test structures with the high-k gate material. The Q-M program has also been modified for extracting the equivalent-oxide-thickness (EOT) and also for investigating the current conduction in the high-k dielectric devices.


Contact Person:
A/Prof WK Chim

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Project: Scanning Electron Acoustic Microscopy for Subsurface Microelectronic Inspection & Failure Analysis.
 
Description:

The current project (in collaboration with Qualcomm Inc. USA) explores the application of SEAM to the non-destructive detection of subsurface features such as voids, cracks and delaminations in semiconductor devices including those using copper/low-K interconnect structures.   It is desireable that a non-invasive diagnostic capability be available for the detection of buried features prior to employing destructive and time-intensive procedures such as delayering and cross-sectioning of suspect samples that can also induce delamination and cracking that can be misinterpreted as failures.    In addition to serving as a flag for the presence of defects, this work also aims to develop further understanding on the complex physical interactions in the formation of signal contrast in SEAM imaging of semiconductor samples.

Based on a scanning electron microscope (SEM), the contrast of the SEAM technique uses the bulk electromechanical properties of the sample due to the electro-thermal-acoustic signal generation mechanism.   Hence, the technique is sensitive to sample parameters such as thermal conductivity, acoustic impedance, Young’s modulus, electrostriction effects, local piezo and ferroelectricity that do not normally produce contrast in conventional electron-beam inspection.   The technique also extends the information-gathering capabilities of the SEM into the deep subsurface regime (up to a few ten’s of microns) for thermal wave-related signal generation mechanisms, compared to the micron range of current high-energy backscattered electron and X-ray analysis.  Additionally, the options of either frequency-derived or time-resolved detection modes provide a means for spatially localizing areas of interest in the Z-axis, thus giving the added potential of depth-profiling or tomography capabilities to the technique.   However, much of these operation modes are still not well-understood and hence require further research into the signal contrast mechanisms which are extremely sample-dependent.

Contact Person: Dr WK Wong

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Project: Scanning Thermal Microscopy for Integrated Circuit Failure Analysis.
 
Description:

Due to the shrinking feature sizes of modern devices, the exact localization of these defects using established thermal failure analysis becomes difficult. The near field Scanning Thermal Microscopy (SThM) is a recently developed Scanning Probe Microscope (SPM) technique that detects specimen thermal features. This project aims to build a SThM for the failure analysis of integrated circuits. This technique will give information about the temperature distributions of the device with a temperature resolution of a few milliKelvins as well as other thermal properties like thermal conductivity in the nanometer scale. It will also provide an understanding of the heat generation mechanism. Different types of devices will be investigated.


Contact Person: Prof JCH Phang

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